题目内容
用库仑滴定法测定水中钙的质量浓度。在50.00mL氨性试液中加入过量的HgNH3Y2-，使其电解产生的Y4-来滴定Ca2+，若电流强度为0.0200A，则到达终点需要3.20min，计算水中CaCO3的质量浓度为多少(以mg·mL-1为单位。)？电解产生Y4-的电极反应为
HgNH3Y2-+NH+4+2e-→Hg+2NH3+HY3-
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在控制阴极电位电解过程中，随着金属离子的析出，金属离子浓度与时间的关系式为______。
电解一价阳离子成为金属在阴极上析出时，若电解至尚剩下0.01%时视为已电解完全，则阴极电位值的变化为多少？
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